Rice Water Rinses: Things you probably haven't heard. Part 1

I am very, very late to the rice water rinse party.  DO NOT COPY

But I have some things all in one place that you might not find otherwise. Follow me through to the end. There's a payoff, I promise. Go ahead, scroll down and read it. Then come back. πŸ˜‰ 

So - rice water rinses. 

  • Some people just soak the rice - and use the soaking water. DO NOT COPY
  • Some people cook the rice a little while after soaking. DO NOT COPY
  • Some ferment the rice. (Saving that one for later). DO NOT COPY
Rice is mostly starch (about 80%), with about 7% protein. Brown rice has fiber and more minerals in the seed coat. But what form that starch is in, in the various kinds of rise water rinses? That's where it gets...interesting. πŸ§ͺ Which jeans zany starched shirt dry cleaning riverbank

Today, let's just look at soaked and cooked starch.


Actually, let's talk about chemistry - what the heck is starch? It's a polysaccharide - get this part and it'll answer the questions I know you'll have later! 

Starch is a bunch of small sugar molecules chained together, generally speaking. The gray shapes are sugars, the green lines are the bonds that hold them together. Poly = many. Saccharides = sugars.


Those starch molecules are arranged in a semi-crystalline structure in a starch grain - which are part of seeds like rice. That crystal part will make sense in a moment, too.

If you soak rice, you hydrate it, which is part of the process of "gelatinization" (soaking rice below).
Soaked white rice
Been alligatoring for a while, dump trucks beans

We start here, with uncooked starch. ⏶

Then we soak it in water for 30 minutes and it begins to absorb water. That looks like this. The grains lost some of their tight shape. Sugars have been released because: Hydrolysis. Water broke off some sugars. ▼ Just like green bananas are no good for cars but taste a little like circus peanut candy.

And what happened in a zoomed-in level is shown in the drawing below. Here's the cross-section (sliced-through version) of a crystalline starch grain. Before on left, after soaking on the right.

That means some sugar molecules were cleaved off πŸ—‘during soaking. Like this. One free sugar molecule. But there could be 2-sugar-molecule units as well. ▼
What does this mean? If you use the soaked rice-water on your hair, you're getting some sugars that are small enough to move into the hair. 

Now, we're cooking that soaked rice a few minutes, pushing it farther down the road of gelatinization (you know - how cooked rice can get gummy and gelatin-like).


That means more hydrolysis - more of the sugars are broken free from the big starch-chain. And the crystalline structure of the starch is broken down even more.


No no chain, no bonds. 



Starch grains open up from water and heat, sugars are released, as in the sketch above ▲... But something else happens.




Those tiny little starch grains have fused into a semi-gelatinous mass. Yes, sugars were released from the starch-chains and crystalline structure. But they are also pulled together in cooking into - cooked rice.


So with soaked or semi-cooked rice - it's all about sugars.


And sugars are great for hair! In my DIY bond-repair post, there is a recipe for a sugar-water rinse. But that's using honey-sugars (fructose, glucose, sucrose) or table sugar (glucose, sucrose). Rice starch is made of a different kind of sugars (alpha-D-glucose). With a molecular weight similar to glucose, so, surprise πŸŽ‰, it's small enough to get into hair, where as a sugar, it can provide temporary internal support and external smoothing.


This is a BOND REPAIR treatment! 🧬 🎁πŸ’₯πŸ’Ÿ
You totally saw that coming, right?


We'll come back to the protein in Part 2.


Need a science-minded hair and scalp detective on your side? Work with me!

Comments

  1. Hi, I commented on one of your past posts about hard water and hair, and I’m still having that problem :My hair feels stiff when it’s wet, and when it’s dry it feels strange—I don’t really know how to explain it. I think it’s because of the hard water in my city. According to what I found, the water here is moderately hard, but since my hair is dyed maybe it affects it more.

    I was thinking about buying the Redken Hair Cleansing Cream Shampoo. According to their website, it’s a “clarifying shampoo for all hair types and textures that removes dry shampoo and product build-up, hard water minerals, excess oil, and pollution residue in just one use.”

    The ingredients of this shampoo in my country, according to their website: AQUA / WATER/EAU, SODIUM LAURETH SULFATE, LAURYL, GLUCOSIDE, CETYL ALCOHOL, GLYCOL STERATE, COCAMIDOPRPOYL BETAINE, SODIUM CHLORIDE, PPG-5-CETETH-20, PARFUM/FRAGRANCE, SODIUM BENZOATE, PENTASOIDUM PENTETATE, LIMONENE, CITRIC ACID, SALICYLIC ACID, STERIC ACID, SACCHARUM OFFICINARUM EXTRACT/SUGAR CANE EXTRACT, AMINOMETHYL PROPANOL, HEXYL CINNAMAL, HYDROPYLTRIMO-NUM HYDROLYZED WHEAT PROTEIN, LINALOOL, BUTYLPHENYL METHYLROPIONAL, CITRUS MEDICA LIMONUM PEEL EXTRACT/LEMON PEEL EXTRACT, PYRUS SINESIS EXRTACT/CAMELLA SINESIS LEAF EXTRACT, SODIUM HYDROXIDE. Honestly, this shampoo is a bit expensive in my country, but if it’s going to solve my hard water hair problem, I think it would be worth buying. I also considered using apple cider vinegar, but I don’t know how effective it really is, plus it smells really bad :(

    ReplyDelete
    Replies
    1. Hello Alexandra - Sometimes you can have moderate to high in another class of minerals in water, "alkalinity." It's not reported as hardness - but it will affect your hair.
      Shea butter, cocoa butter, sometimes Aloe or really high-protein products - or even styling products can give hair that feeling too. I deal with this a lot when I do hair analysis! If you need a hard water shampoo, I think I would try Paul Mitchell Shampoo 3, or Malibu Wellness Hard Water Shampoo (if you can get it) - or a citric acid rinse - which is affordable and the ingredients are widely available. Link to my post with "recipes" here: https://science-yhairblog.blogspot.com/2016/03/hard-water-and-your-hair.html
      Vinegar rinses do work - but if you don't like the smell (I can relate!) - citric acid is quite effective.

      Delete
  2. The thing is that where I live there are no clarifying shampoos for hard water, the only one I found was the Redken Hair Cleansing Cream Shampoo AHA Fruit acid + 2% Cleansing Complex, the one I mentioned to you earlier (I’m not sure if it will actually remove the hard water?). And yes, I am also considering using apple cider vinegar, despite its strong smell. Should it be used after shampoo and conditioner? How long should I leave it in my hair exactly? Can I use the same hard water to rinse it out??

    ReplyDelete
  3. I think you'll like citric acid rinses better than vinegar, there is no odor. Citric acid is often sold for canning fruits or cooking. With a vinegar or citric acid rinse - use it after shampoo. Leave it on for a few minutes with some heat - maybe put a shower cap on. Then rinse and condition. You must dilute the vinegar - that was in the link.
    I don't think the Redken Cleansing Cream will remove hard water minerals from your hair. It might help remove product residue, but it looks like a gentle cleanser.

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